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Issue 4 (1), pp. 60-73, 2026

Article

Features of the tunneling conductance of break-junctions in underdoped BaFe2-xNixAs2 single crystals

I. A. Nikitchenkov

Faculty of Physics, Lomonosov Moscow State University, Leninskie Gory, 1, 119991, Moscow, Russia

P. N. Lebedev Physical Institute of the RAS, Leninsky prospect, 53, 119991, Moscow, Russia

A. D. Lomonosova

P. N. Lebedev Physical Institute of the RAS, Leninsky prospect, 53, 119991, Moscow, Russia

S. A. Kuzmichev

Faculty of Physics, Lomonosov Moscow State University, Leninskie Gory, 1, 119991, Moscow, Russia

K. S. Pervakov

P. N. Lebedev Physical Institute of the RAS, Leninsky prospect, 53, 119991, Moscow, Russia

V. A. Vlasenko

P. N. Lebedev Physical Institute of the RAS, Leninsky prospect, 53, 119991, Moscow, Russia

DOI: https://doi.org/10.62539/2949-5644-2026-4-1-60-73

Abstract

The features of the I(V) and dI(V)/dV characteristics of tunneling break-junctions formed in underdoped BaFe2-xNixAs2 single crystals with x ≈ 0.07 and 0.08 and critical temperatures Tc ≈ 16 and 19 K, respectively, were studied at various temperatures. A reproducible nonlinearity of the I(V) characteristics and tunneling conductance was observed both below and above Tc. This behavior is unusual for contacts based on conventional superconductors and is not directly related to superconducting properties. The nonlinearity is characterized by the presence of maxima and minima in the dI(V)/dV-spectra located at bias voltages Vmax ≈ 21 mV, Vmin ≈ 40 mV for compounds with x ≈ 0.07 and Vmax ≈ 19 mV, Vmin ≈ 48 mV for x ≈ 0.08. Below Tc, features caused by incoherent Andreev reflections are observed on the background of this nonlinearity. The energy parameters of the superconducting state were estimated from the analysis of the Andreev features of dI(V)/dV spectra: the magnitude of the large superconducting gap 2ΔL(0) = 5.8–7.9 meV and the small superconducting gap 2ΔS(0) = 2.3 meV for BaFe1.92Ni0.08As2 compounds, as well as the large superconducting gap 2ΔL(0) = 4.5–8.5 meV for BaFe1.93Ni0.07As2 (the range of the 2ΔL(0) values relates to possible anisotropy of the superconducting condensate properties in k-space). The origin of the observed effects is discussed.

Keywords: high-temperature superconductivity, pnictides, tunneling spectroscopy, electronic density of states

References

[1] Y. Kamihara, H. Hiramatsu, M. Hirano, et al. Iron-Based Layered Superconductor: LaOFeP. J. Am. Chem. Soc. 128, 10012 (2006). DOI: 10.1021/ja063355c
[2] J. Paglione and R. L. Greene. High-temperature superconductivity in iron-based materials Nature Phys. 6, 645 (2010). DOI: 10.1038/nphys1759
[3] H. Hosono, A. Yamamoto, H. Hiramatsu, and Y. Ma. Recent advances in iron-based superconductors toward applications. Materials Today 21, 278 (2018). DOI: https://doi.org/10.1016/j.mattod.2017.09.006
[4] X. Lu, Phase Diagram and Magnetic Excitations of BaFe2-xNixAs2: Springer (2017).
[5] S. Ideta, T. Yoshida, I. Nishi, et al. Dependence of Carrier Doping on the Impurity Potential in Transition-Metal-Substituted FeAs-Based Superconductors. Physical Review Letters 110, 100700 (2013). DOI: 10.1103/PhysRevLett.110.107007
[6] D.V. Evtushinsky, V.B. Zabolotnyy, L. Harnagea, et al. Electronic band structure and momentum dependence of the superconducting gap in Ca1u2212 xNaxFe2As2 from angle-resolved photoemission spectroscopy. Physical Review B-Condensed Matter and Materials Physics 87, 0945501 (2013). DOI: 10.1103/PhysRevB.87.094501
[7] A.A. Kordyuk, V.B. Zabolotnyy, D.V. Evtushinsky et al. Electronic band structure of ferro-pnictide superconductors from ARPES experiment. Journal of superconductivity and novel magnetism 26, 2837 (2013). DOI: 10.1007/s10948-013-2210-8
[8] T. E. Kuz’micheva, S. A. Kuz’michev, K. S. Pervakov, V. A. Vlasenko. Sravnenie shchelevoj struktury sverhprovodyashchih pniktidov BaFe2-xNixAs2 nedo- i peredopirovannogo sostava. Pis’ma v Zhurnal eksperimental’noj i teoreticheskoj fiziki 118, 526 (2023). DOI: 10.31857/S1234567823190096
[9] T.E. Kuzmicheva, A.V. Muratov, S.A. Kuzmichev, et al. On the structure of the superconducting order parameter in high-temperature Fe-based superconductors. Physics-Uspekhi 60, 419 (2017). DOI: 10.3367/UFNe.2016.10.038002
[10] T. E. Kuz’micheva, Yu. A. Aleshchenko, P. I. Bezotosnyj i dr. Eksperimental’nye i teoreti-cheskie issledovaniya pniktidov semejstva BaFe2As2 s elektronnym zameshcheniem (Miniobzor). Pis’ma v Zhurnal eksperimental’noj i teoreticheskoj fiziki 121, 432 (2025). DOI: 10.31857/S0370274X25030184
[11] Q. Si, R. Yu & E. Abrahams. High-temperature superconductivity in iron pnictides and chalcogenides. Nature Reviews Materials 1, 16017 (2016). DOI: 10.1038/natrevmats.2016.17
[12] S.J. Moon, A.A. Schafgans, S. Kasahara, et al. Infrared measurement of the pseudogap of P-doped and Co-doped high-temperature BaFe2As2 superconductors. Physical review letters 109, 027006 (2012). DOI: 10.1103/PhysRevLett.109.027006
[13] T. Shimojima, T. Sonobe, W. Malaeb, et al. Pseudogap formation above the superconducting dome in iron pnictides. Physical Review B 89, 045101 (2014). DOI: 10.1103/PhysRevB.89.045101
[14] I.I. Mazin, D.J. Singh, M.D. Johannes, and M.H. Du. Unconventional Superconductivity with a Sign Reversal in the Order Parameter of LaFeAsO1-xFx. Physical Review Letters 101, 057003 (2008). DOI: 10.1103/PhysRevLett.101.057003
[15] M.M. Korshunov. Superconducting state in iron-based materials and spin-fluctuation pairing theory. Uspekhi Fizicheskih Nauk 184, 882 (2014). DOI: 10.3367/ufnr.0184.201408h.0882
[16] M. Yi, D.H. Lu, J.-H. Chu, et al. Symmetry-breaking orbital anisotropy observed for detwinned Ba(Fe1-xCox)2As2 above the spin density wave transition. Proceedings of the National Academy of Sciences. 108, 3878 (2011). DOI: 10.1073/pnas.1015572108
[17] R.M. Fernandes, A.V. Chubukov, J. Schmalian. What drives nematic order in iron-based superconductors? Nature physics 10, 97 (2014). DOI: 10.1038/nphys2877
[18] Q. Hu, Y. Zheng, H. Xu, et al. Evidence for saddle point-driven charge density wave on the surface of heavily hole-doped iron arsenide superconductors. Nat Commun 16, 253 (2025). DOI: 10.1038/s41467-024-55368-7
[19] A.V. Tsvetkova, Ya.I. Rodionov, & P.D. Grigoriev. Resistivity, density of electronic states, and superconducting transition temperature in density wave compounds with imperfect nesting. Physical Review B 111, 205141 (2025). DOI: 10.1103/physrevb.111.205141
[20] F. Massee, Y.K. Huang, J. Kaas, et al. Pseudogap-less high-T c superconductivity in BaCoxFe2u2212xAs2. EPL (Europhysics Letters) 92, 57012 (2010). DOI: 10.1209/0295-5075/92/57012
[21] L. Shan, J. Gong, Y.-L. Wang, et al. (2012). Evidence of a Spin Resonance Mode in the Iron-Based Superconductor Ba0.6K0.4Fe2As2 from Scanning Tunneling Spectroscopy. Physical Review Letters 108, 227002 (2012). DOI: 10.1103/physrevlett.108.227002
[22] Z. Wang, H. Yang, D. Fang, B. Shen, et al. (2012). Close relationship between superconductivity and the bosonic mode in Ba0.6K0.4Fe2As2 and Na(Fe0.975Co0.025)As. Nature Physics 9, 42 (2012). DOI: 10.1038/nphys2478
[23] D. Fang, X. Shi, Z. Du, et al. Observation of a van Hove singularity and implication for strong coupling induced Cooper pairing in KFe2As2. Phys. Rev. B 92, 144513 (2015).
[24] H.Z. Arham, C.R. Hunt, W.K. Park, et al. Detection of orbital fluctuations above the structural transition temperature in the iron pnictides and chalcogenides. Physical Review B 85, 214515 (2012). DOI: 10.1103/physrevb.85.214515
[25] I.A. Nikitchenkov, S.A. Kuz’michev, A.D. Il’ina i dr. (2024). Tunnel’naya spektrosko-piya BaFe2−hNihAs2 s variaciej stepeni dopirovaniya v sverhprovodyashchem i normal’nom sosto-yaniyah. Zhurnal eksperimental’noj i teoreticheskoj fiziki 166, 834 (2024). DOI: 10.31857/s0044451024120071
[26] I.A.Nikitchenkov, A.D.Ilina, V.M. Mikhailov, ey al, Tunneling spectroscopy of slightly overdoped pnictides BaFe1.88Ni0.12As2 in the superconducting and normal state. Vestnik Moskovskogo Universiteta, Seriya 3: Fizika, Astronomiya 78, 234050 (2023). DOI: 10.55959/msu0579-9392.78.2340501
[27] I. Giaever, K. Megerle. Study of superconductors by electron tunneling. Physical Review 122, 1101 (1961). DOI: 10.1103/PhysRev.122.1101
[28] K.S. Pervakov, V.A. Vlasenko, E.P. Khlybov, et al. Bulk magnetization and strong intrinsic pinning in Ni-doped BaFe2As2 single crystals. Supercond. Sci. Technol. 26, 015008 (2013). DOI: 10.1088/0953-2048/26/1/015008
[29] V.A. Vlasenko, O.A. Sobolevskiy, A.V. Sadakov, et al. Systematic Study of Vortex Pinning and a Liquid-Glass Phase Transition in BaFe2u2013xNixAs2 Single Crystals. JETP Letters. 107, 121 (2018). DOI: 10.1134/S0021364018020042
[30] T.E. Kuzmicheva, S.A. Kuzmichev, K.S. Pervakov, V.A. Vlasenko. Superconducting order parameters in overdoped BaFe1.86Ni0.14As2 revealed by multiple Andreev reflection spectroscopy of planar break junctions. Phys. Rev. B 104, 174512 (2021). DOI: 10.1103/PhysRevB.104.174512
[31] A.V. Sadakov, A.V. Muratov, S.A. Kuzmichev et al. Determination of the Superconducting Order Parameter of BaFe1.92Ni0.08As2 Weakly Underdoped Pnictides by Two Complementary Techniques. JETP Lett. 116, 708 (2022). DOI: 10.1134/S0021364022602093
[32] J. Moreland, J.W. Ekin. Electron Tunneling Experiments Using Nb-Sn Break Junctions. J. Appl. Phys. 58, 3888 (1985).
[33] S.A. Kuzmichev, T.E. Kuzmicheva. “Break-junction” technique in application to layered superconductors (Review Article). Low. Temp. Phys. 42, 1008 (2016). DOI: 10.1063/1.4971437
[34] M. Octavio, M. Tinkham, G.E. Blonder, T.M. Klapwijk. Subharmonic energy-gap structure in superconducting constrictions. Phys. Rev. B 27, 6739 (1983). DOI: 10.1103/PhysRevB.27.6739
[35] D. Averin and A. Bardas. ac Josephson Effect in a Single Quantum Channel. Phys. Rev. Lett. 75, 1831 (1995). DOI: 10.1103/PhysRevLett.75.1831
[36] R. Kummel, U. Gunsenheimer, and R. Nicolsky. Andreev scattering of quasiparticle wave packets and current-voltage characteristics of superconducting metallic weak links. Phys. Rev. B 42, 3992 (1990). DOI: 10.1103/PhysRevB.42.3992
[37] Z. Popović, S. Kuzmichev, T. Kuzmicheva. Amplitudes of minima in dynamic conductance spectra of the SNS Andreev contact. J. Appl. Phys. 128, 013901 (2020). DOI: 10.1063/5.0010883
[38] T.P. Devereaux, P. Fulde. Multiple Andreev scattering in superconductor-normal metal-superconductor junctions as a test for anisotropic electron pairing. Phys. Rev. B 47, 14638 (1993). DOI: 10.1103/PhysRevB.47.14638
[39] J. Fink, J. Nayak, E. D. L. Rienks, et al. Evidence of hot and cold spots on the Fermi surface of LiFeAs. Physical Review B 99, 245156 (2019). DOI: 10.1103/PhysRevB.99.245156
[40] Yu.V. Sharvin. A Possible Method for Studying Fermi Surfaces. Sov. Phys. JETP 21, 655 (1965).
[41] G. Wexler. The size effect and the non-local Boltzmann transport equation in orifice and disk geometry. Proc. Phys. Soc. 89, 927 (1966). DOI: 10.1088/0370-1328/89/4/316
[42] W.-C. Lee, & P.W. Phillips. (2012). Non-Fermi liquid due to orbital fluctuations in iron pnictide superconductors. Physical Review B 86, 245113 (2012). DOI: 10.1103/physrevb.86.245113